In situ Transfer of Parahydrogen-Induced Nuclear Spin Polarization—Structural Characterization of Hydrogenation Intermediates

2000 ◽  
Vol 39 (20) ◽  
pp. 3701-3703 ◽  
Author(s):  
Patrick Hübler ◽  
Joachim Bargon
Keyword(s):  
Spin Polarization ◽  
Structural Characterization ◽  
Nuclear Spin ◽  
Nuclear Spin Polarization

Dynamical Nuclear Polarization

2018 ◽  
Author(s):  
M. M. Glazov
Keyword(s):  
Spin Polarization ◽  
Nuclear Spin ◽  
Nuclear Polarization ◽  
Magnetic Moments ◽  
Nonlinear Effects ◽  
Many Body ◽  
Nuclear Spin Polarization ◽  
Optical Resonances ◽  
Dynamical Nuclear Polarization ◽  
Temperature Concept

The transfer of nonequilibrium spin polarization between the electron and nuclear subsystems is studied in detail. Usually, a thermal orientation of nuclei in magnetic field is negligible due to their small magnetic moments, but if electron spins are optically oriented, efficient nuclear spin polarization can occur. The microscopic approach to the dynamical nuclear polarization effect based on the kinetic equation method, along with a phenomenological but very powerful description of dynamical nuclear polarization in terms of the nuclear spin temperature concept is given. In this way, one can account for the interaction between neighbouring nuclei without solving a complex many-body problem. The hyperfine interaction also induces the feedback of polarized nuclei on the electron spin system giving rise to a number of nonlinear effects: bistability of nuclear spin polarization and anomalous Hanle effect, dragging and locking of optical resonances in quantum dots. Theory is illustrated by experimental data on dynamical nuclear polarization.

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

scholarly journals Dynamics of nuclear spin polarization induced and detected by coherently precessing electron spins in fluorine-doped ZnSe

2016 ◽  
Vol 93 (8) ◽  
Author(s):  
F. Heisterkamp ◽  
E. Kirstein ◽  
A. Greilich ◽  
E. A. Zhukov ◽  
T. Kazimierczuk ◽  
...  
Keyword(s):  
Spin Polarization ◽  
Nuclear Spin ◽  
Electron Spins ◽  
Nuclear Spin Polarization

Magnetic field dependence of fluorine-19 nuclear spin polarization. The system tetrafluorobenzoquinone-tetrafluorohydroquinone

1982 ◽  
Vol 104 (22) ◽  
pp. 5878-5883 ◽  
Author(s):  
Richard S. Hutton ◽  
Heinz D. Roth ◽  
Marcia L. Manion Schilling ◽  
Anthony M. Trozzolo ◽  
Thomas M. Leslie
Keyword(s):  
Magnetic Field ◽  
Spin Polarization ◽  
Field Dependence ◽  
Nuclear Spin ◽  
Magnetic Field Dependence ◽  
Nuclear Spin Polarization

Effective collinear optical pumping for nuclear spin polarization

2014 ◽  
Vol 31 (10) ◽  
pp. 2278 ◽  
Author(s):  
Sung Jong Park ◽  
Taeksu Shin ◽  
Ju Hahn Lee ◽  
Gi Dong Kim ◽  
Yong Kyun Kim
Keyword(s):  
Spin Polarization ◽  
Nuclear Spin ◽  
Optical Pumping ◽  
Nuclear Spin Polarization
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